33. Jon Hamm

As characters go, they don't come much smoother talking or looking than Don Draper, as memorably played by Jon Hamm in 'Mad Men.' Draper is the sort of salesman who could persuade you to buy sand in the middle of a desert, and has the kind of finely-tailored look that oozes sophistication and class. Based on this photo, Hamm was already in training for the part from his teenage years onward. Most boys on prom night look like kids in their father's suits. Hamm doesn't.

He hasn't quite got the million-dollar smile down yet - that will come with time - but he's clearly happy to be posing for pictures with his date. They've even managed to hold hands without it appearing to be awkward. That's how it's supposed to work! We can always rely on Hamm to show everybody how it's done - even if he wouldn't buy anything from him.

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